You are using the TP 210 balancer w/ the cable to the 1010 charger right? I don't have one to look at so going from memory.
Set the charger to the correct cell count
Set the charge rate (Amps)
Connect the balance leads to the 210 balancer
( one end is marked group A the other end is marked group B. One end has 2 6pin connectors the other end has a 6pin and a 4pin connector)
Use the end with the 6 and 4 pin connector for your 6S pack.
Connect the main power lead
Push start and hold till the charger beeps, it'll check cell count ect. Then it will start the charge. Pushing either the + or - button
after the charge has started will show the voltage of each cell connected to the balancer.
As best i can remember..
Here is a link to the balancer directions also..
Team Synergy Field Representative / Thunder Power